Chapter 1 :Introduction...1

Chapter 2: Survey of Methods for the Elucidation of the Stereochemistry of Coordination... 15

Chapter 3: Theoretical Bases for the Coordination Geometries of Metal Ions... 20

Chapter 4: General Concepts in Topographic Stereochemistry of Coordination Compounds... 35

Chapter 5: Topographical Stereochemistry of Mononuclear Coordination Units... 75

Chapter 6: Topographical Stereochemistry of Polynuclear Coordination Units... 177

Chapter 7: The Stereochemical Course of Reactions of Metal Complexes... 202

Alexander Von Zelewsky

100 years after the formulation of the coordination theory by Alfred Werner, stereochemical considerations are again at the center of interest in the development of metal complexes. Reflecting this renewed interest, Stereochemistry of Coordination compoun ds explains the modern aspects of this area of chemistry, firstly by introducing the stereochemistry of various coordination geometries. The later chapters go on to address applications in the field of polynuclear species and stereochemical aspects of rea ctions, including enantioselective catalysis. Provides: A systematic introduction to the structures of molecular species with atoms of various coordination number, focusing on the most important octahedral case A presentation of the principles that are applied to produce molecular helices, chains and knots An account of the historical background of the Stereochemistry of coordination compounds electronic figure files that are available on the Internet.

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